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采用钠萘作还原剂制备C60 负一价离子 ,计量易控制 ,方法简便 .利用复分解反应首次合成了十六烷基三甲基铵的C60 盐 ,产物经紫外可见 近红外光谱 (V NIR)、红外光谱 (IR)、电喷雾电离质谱 (ESI MS)表征 ,研究了其电子顺磁共振谱 (ESR)性质和被空气氧化的过程
The preparation of C60 negative monovalent ions using sodium naphthalene as reductant is easy to measure and control, and the method is simple and convenient. The C60 salt of cetyltrimethylammonium was synthesized for the first time by metathesis reaction. The product was characterized by UV-Visible Near Infrared Spectroscopy (V NIR) Infrared spectroscopy (IR) and electrospray ionization mass spectrometry (ESI MS) were used to characterize the electronic paramagnetic resonance spectroscopy (ESR) and the process of air oxidation