Distribution and health risk assessment of organochlorine pesticides (OCPs) in industrial site soils

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A field survey was conducted in a contaminated industrial site in south Beijing, China to investigate theconcentrations and distribution of the organochlorine pesticides (α-, β-, γ-, δ-HCH, p,p’-DDT, p,p’-DDE, p,p’-DDD and o,p’-DDT) in the profiles of soil, and a health risk assessment was carried out with CalTOX multimedia exposure model. Results showed that mean concentrations of total hexachlorocyclohexane isomers (HCHs) and total dichlorodiphenyltrichloroethane isomers (DDXs) in soils ranged in 13.19-148.71 mg/kg, and 3.02-67.42 mg/kg, respectively. Organochlorine pesticides (OCPs) concentration peaked at the surface and declined in soil profile with depth and the amounts of HCHs in three profiles of soil were larger than DDXs. Composition analysis indicated that there was a trend of degradation of OCPs in the site, but the mean of HCHs and DDXs concentration were over the state wing standard limit (HCHs, 0.50 mg/kg; DDXs, 0.50 mg/kg). According to current land use development, health risk assessment with CalTOX and Monte Carlo analysis showed that health risks mainly came from two exposure pathways: dermal uptake and inhalation, and that the total risk values all exceeded the general acceptable health risk value (10-6). The sensitivity analysis indicated that five parameters significantly contributed to total risk.
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