【摘 要】
：
The catalytic activities of nine neutral nickel and palladium a-acetylide complexes [M=(C=CR)2(PR’3)2)M=Ni,Pd; R=Ph,CH2OH,CH2OOCH3,CH2OOCPh,CH2OOCPhOH-o; R’=
【机 构】
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Department of Chemistry and Chemical Engineering,Suzhou University,Jiangsu 215006, China,Department
【出 处】
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Chinese Journal of Chemistry
论文部分内容阅读
The catalytic activities of nine neutral nickel and palladium a-acetylide complexes [M=(C=CR)2(PR’3)2)M=Ni,Pd; R=Ph,CH2OH,CH2OOCH3,CH2OOCPh,CH2OOCPhOH-o; R’=Ph,Bu] are compared.Among them,Ni(Cs=CPh)2-(PBuj)2 shows the highest catalytic activity and gives the polystyrene with high molecular weight(Mw=188800)and a syndio-rich microstructure.The catalytic behavior of transition metal acetylides is related to metal,phosphine,and alkynyl ligands bonded to the metal atoms.
M = Ni, Pd; R = Ph, CH2OH, CH2OOCH3, CH2OOCPh, CH2OOCPhOH-o; R (= Cph) 2- (PBuj) 2 shows the highest catalytic activity and gives the polystyrene with high molecular weight (Mw = 188800) and a syndio-rich microstructure. catalytic behavior of transition metal acetylides is related to metal, phosphine, and alkynyl ligands bonded to the metal atoms.
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