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以钛酸丁酯为ＴｉＯ２前驱体，使ＴｉＯ２均匀分散于纯硅介孔分子筛ＭＣＭ－４１的介孔孔道内表面，利用ＴｉＯ２光学性质将ＡｕＣｌ－４还原为Ａｕ（０）并组装于氧化钛修饰的ＭＣＭ－４１孔道中．对所合成的Ａｕ负载的氧化钛修饰的ＭＣＭ－４１进行了ＸＲＤ，ＸＰＳ，Ｎ２吸附－脱附曲线，及固体ＵＶ－Ｖｉｓ漫反射等多种结构表征．由ＸＰＳ谱和固体ＵＶ－Ｖｉｓ漫反射吸收光谱的ｐｌａｓｍｏｎ吸收峰证明Ａｕ团簇呈现０价的金属状态．
Titanium tetrabutoxide (TiO2) was used as a precursor of TiO2 to uniformly disperse TiO2 on the inner surface of mesoporous silica mesoporous MCM-41. AuCl-4 was reduced to Au (0) by optical properties of TiO2 and assembled into titanium oxide In the MCM-41 well. The synthesized Au-supported titanium oxide modified MCM-41 was characterized by XRD, XPS, N2 adsorption-desorption curves and solid-state UV-Vis diffuse reflectance spectroscopy. The plasmon absorption peaks of the XPS spectrum and the solid UV-Vis diffuse reflection absorption spectrum demonstrate that the Au cluster assumes a 0-valent metal state.