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Cu(I)的配合物有广泛的用途而受到人们的普遍关注.利用CuCl2和过量的铜屑在浓盐酸介质中加热即全部生成H[CuCl2],将其直接倾入蒸馏水中便可得到大量CuCl沉淀,由此制备Cu(I)配合物方法简单.CuCl为具有闪锌矿型结构的分子晶体,遇配体溶解生成稳定的Cu(I)配合物CuLn,它们与Cu(I)离子的性质不同,能在水溶液中稳定存在,这就提供了供应水溶液中+1氧化态铜化合物的一种方法,使Cu(I)配合物的用途大为扩展.
Cu (I) complexes have been widely used for a wide range of people’s attention by the use of CuCl2 and excess copper scrap in concentrated hydrochloric acid medium that is heated to generate H [CuCl2], which will be poured directly into distilled water can be a lot of CuCl precipitates, Cu (I) complexes are easy to prepare.CuCl is a molecular crystal with sphalerite structure, and when CuCl is dissolved, Cu (I) The properties are different and can exist stably in aqueous solution, which provides a method for supplying the +1 oxidation state copper compound in aqueous solution, which greatly expands the use of Cu (I) complex.