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The design and synthesis of novel dendritic-linear block copolymers were described. The copolymers were synthesized by atom transfer radical polymerization (ATRP) using dendritic polyarylether 2-bromoisobutyrate macroinitiator. ATRP carried out in bulk with CuBr/bipy catalyst at 120癈, yielded well-defined block copolymers with polydispersities less than 1.36.
The designs and synthesis of novel dendritic-linear block copolymers were described. The copolymers were synthesized by atom transfer radical polymerization (ATRP) using dendritic polyarylether 2-bromoisobutyrate macroinitiator. ATRP carried out in bulk with CuBr / bipy catalyst at 120 癈, yielded well -defined block copolymers with polydispersities less than 1.36.