采用一锅法,过硫酸铵既作为氧化剂又作为引发剂,设计合成出高产量水溶性六元瓜环桥连丙烯酸聚合物。所合成的六元瓜环桥连丙烯酸聚合物通过核磁氢谱,碳谱,二维核磁,红外,凝胶色谱和扫描电镜等表征确认。实验结果显示聚丙烯酸链可以以一种受控的模式通过自由基聚合接枝到六元瓜环表面。 Using one-pot method, ammonium persulfate both as an oxidant and as an initiator, designed and synthesized a high yield of water-soluble six yuan melon ring bridged acrylic polymer. The synthesized six-membered ring bridged acrylic acid polymer was confirmed by 1H NMR, GC, 2D NMR, IR, gel chromatography and scanning electron microscopy. The experimental results show that the polyacrylic acid chains can be grafted onto the surface of a six-membered ring via free-radical polymerization in a controlled manner.