Electrochemical Determination of Trace Amounts of Lead (Ⅱ) and Cadmium (Ⅱ) at a Calix[6]arene Modifi

来源 :Wuhan University Journal of Natural Sciences | 被引量 : 0次 | 上传用户:a57556836
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An electrochemical method for the simultaneous determination of lead(Ⅱ) and Cadmium(Ⅱ) with a calixarene modified carbon paste electrode (CPE) has been developed. Pb 2+ and Cd 2+ were accumulated at the surface of the modified electrode via formation of chemical complexes with calixarene, and reduced at 1.40 V. During the following anodic potential sweep, reduced lead and cadmium were oxidized, and two well-defined striping peaks appeared at about -0.60 V and -0.84 V. Compared with a bare carbon paste electrode, the calixarene modified CPE greatly improves the sensitivity of determining lead and cadmium. The stripping peak currents change linearly with the concentration of Pb 2+ 3.0×10 -8 -8.0×10 -6 mol5L -1 and with that of Cd 2+ 6.0×10 -8 -1.0×10 -5 mol5L -1 . The detection limits of Pb 2+ and Cd 2+ are found to be 8.0×10 -9 mol5L -1 and 2.0×10 -8 mol5L -1 , respectively. The modified carbon paste electrode was applied to determine trace levels of lead and cadmium in water samples. Comparing with that of atomic absorption spectrometry, the results suggests that the calixarene modified CPE has great potential for the practical sample analysis. An electrochemical method for the simultaneous determination of lead (II) and Cadmium (II) with a calix arene modified carbon paste electrode (CPE) has been developed. Pb 2+ and Cd 2+ were accumulated at the surface of the modified electrode via formation of chemical complexes with calix arene, and reduced at 1.40 V. During the following anodic potential sweep, reduced lead and cadmium were oxidized, and two well-defined striping peaks were at about -0.60 V and -0.84. with a bare carbon paste electrode, the calix are are modified CPE substantial improves the sensitivity of determining lead and cadmium. The stripping peak currents change linearly with the concentration of Pb 2+ 3.0 × 10 -8 -8.0 × 10 -6 mol 5L -1 and with that of Cd 2+ 6.0 × 10 -8 -1.0 × 10 -5 mol 5L -1. The detection limits of Pb 2+ and Cd 2+ are found to be 8.0 × 10 -9 mol 5L -1 and 2.0 × 10 -8 mol 5L -1, respectively. The modif ied carbon paste electrode was applied to determine trace levels of lead and cadmium in water samples. Comparing with that of atomic absorption spectrometry, the results suggests that the calix arene modified CPE has great potential for the practical sample analysis.
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