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A new structural copper (Ⅱ) monosalicylate, Cu(OC6 H4 CO2)·H2 O, was synthesized by the rheological phase reaction method from salicylic acid and copper oxide in 1:1 mole ratio. The structure was characterized by powder X-ray diffraction, IR and thermogravimetry. The Cu (OC6 H4 CO2)·H2O belongs to monoclinic system, with cell dimension: a = 2. 136 28(67), b=0.657 84(22), c=1.594 09(50) nm, β= 108.434(25) , V=2. 125 28(83) nm3 , Z=12, Dcalc = 2.041 kg·L-1 , Dobs = 2. 003 kg·L-1. The crystal water was lost at 96-250℃. The determined magnetic moment and magnetic susceptibility were 1. 947 B. M. and 6. 546×10-6 (287.20 K), respectively.
A new structural copper (Ⅱ) monosalicylate, Cu (OC6 H4 CO2) · H2 O, was synthesized by the rheological phase reaction method from salicylic acid and copper oxide in 1: 1 mole ratio. The structure was characterized by powder X-ray diffraction , IR and thermogravimetry. The Cu (OC6 H4 CO2) · H2O belongs to a monoclinic system with a cell dimension of a = 2. 136 28 (67), b = 0.657 84 (22), c = 1.594 09 B = 108.434 (25), V = 2.125 28 (83) nm3, Z = 12, Dcalc = 2.041 kg · L-1 and Dobs = 2. 003 kg · L-1. 250 ° C. The determined magnetic moment and magnetic susceptibility were 1. 947 BM and 6. 546 × 10-6 (287.20 K), respectively.