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Treatment of deprotonated N,N′-bis(4-methyl-2-benzothiazolyl)-2, 6-pyridicarboxamide (L2-) with CoCl2·6H2O yields the mononuclear complex, (Et4N)2·0.5H2O. Single crystal X-ray structural determination has been carried out for the complex, crystal system: Monoclinic, space group: P21/c, a=1.444(1) nm, b=1.969(1) nm, c=2.448(1) nm, β=118.02(1)°, V=6.143 0(15) nm3, Z=4. In this complex, the central Co atom is in an octahedron environment, with four deprotonated amide-N atoms in the equatorial plane and two pyridine-N atoms in the axial positions. CCDC: 252558.
Treatment of deprotonated N, N’-bis (4-methyl-2-benzothiazolyl) -2,6-pyridicarboxamide (L2-) with CoCl2 · 6H2O yields the mononuclear complex, (Et4N) 2 · 0.5H2O. Single crystal X-ray Structural determination has been carried out for the complex crystal system: Monoclinic, space group: P21 / c, a = 1.444 (1) nm, b = 1.969 (1) nm, 1) °, V = 6.143 0 (15) nm3, Z = 4. In this complex, the central Co atom is in an octahedron environment, with four deprotonated amide-N atoms in the equatorial plane and two pyridine-N atoms in the axial positions. CCDC: 252558.