Correlative study of the Ordovician chitinozoan biostratigraphy in China with graptolite and conodont biozones, and comprehensive analysis of the sequence- and event-stratigraphic indicated that 17 chitinozoan zones and 5 main chitinozoan diversification events subsequently occurring could be recognized in the Ordovician System of China. The 5 events comprise: event 1-appearance of the earliest Ordovician chitinozoans, event 2-appearance of C. symmetrica, event 3-juvenile radiation of chitinozoans, event 4-appearance of chitinozoans with high diversity, and event 5-development of chitinozoans of deep-water facies. The age and feature of each event and its relation with the sea-level change and other geological event are discussed.