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Two novel manganese(Ⅱ)complexes,[Mn(pmadH2)2(3-Sb)]n(1)and{[Mn(pmadH2)(Hssal)(H2O)]·2H2O}n(2)(pmadH2=2-pyrimidineamidoxime,3-Sb=3-sulfobenzoate dianion,H3ssal=5-sulfosalicylic acid),have been successfully obtained.The two complexes were characterized