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在深海环境中,海水的压力、温度和含氧量等因素会影响有机涂层的使用寿命.本文研究模拟深海环境对涂层带有人工破损时,涂覆以改性厚浆环氧防锈涂层的907A钢试样在天然海水中的电化学阻抗谱响应特征和涂层耐蚀性能变化.结果表明,在相同破损率和相同浸泡时间条件下,与常压下试样相比,处于2.5 MPa的压力下试样的阻抗幅值显著变小,而且随浸泡时间延长,试样的涂层电容呈增加趋势,极化电阻不断减小,证实了海水压力加速了涂层的失效过程.同时表明,在模拟深海环境中运用电化学交流阻抗对研究有机涂层失效过程是可行的.
In the deep sea environment, the seawater pressure, temperature and oxygen content and other factors will affect the life of the organic coating.In this paper, simulation of deep sea environment on the coating with artificial damage, coated with a modified thick epoxy antirust The electrochemical impedance spectroscopy (EIS) response characteristics of the coated 907A steel in natural seawater and the corrosion resistance of the coating were investigated. The results show that under the same damage rate and same immersion time, Under 2.5 MPa pressure, the impedance of the sample decreases significantly. With the increase of immersion time, the coating capacitance of the sample increases and the polarization resistance decreases. It is confirmed that the seawater pressure accelerates the failure process of the coating. At the same time, it is indicated that the application of electrochemical AC impedance in simulated deep-sea environment is feasible to study the failure process of organic coatings.