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合成了两种烯丙基封端的含酰亚胺基的致介晶性单体,并与甲基丙烯酸甲酯共聚,制得了一系列含酰亚胺键的侧链液晶聚合物.应用FTIR、GPC、DTA及热台偏光显微镜进行了表征.研究表明,随着致介晶性单体含量减少,其液晶特征从点状织构向条状、丝状织构转变.
Two allyl-terminated imide group-containing mesogenic monomers were synthesized and copolymerized with methyl methacrylate to prepare a series of side-chain liquid crystal polymers with imide bond. The samples were characterized by FTIR, GPC, DTA and hot stage polarization microscope. The results show that with the reduction of the content of mesogenic monomers, the liquid crystal features change from dot-like texture to strip-like and filamentous texture.