Thermal and luminescent properties of 2 μm emission in thulium-sensitized holmium-doped silicate-ger

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In this paper, we present the luminescent properties of Tm3 ∕Ho3 co-doped new glass. A series of silicategermanate glass was prepared by the conventional melt-quenching method. In the Tm3 ∕Ho3 co-doped silicategermanate glass, a strong emission of 2 μm originating from the Ho3 :5I7 → 5I8 transition can be observed under conventional 808 nm pumping. The characteristic temperatures, structure, and absorption spectra have been measured. The radiative properties of Ho33 in the prepared glass were calculated. The emission cross section of Ho33 ions transition can reach 4.78 × 10?21 cm2 around 2 μm, and the FWHM is as high as 153 nm. The energy transfer efficiency between Ho3 and Tm3 has a large value (52%), which indicates the Tm3 ∕Ho3 co-doped silicategermanate glass is a suitable candidate for the 2 μm laser. Moreover, the energy transfer mechanism between Tm3 and Ho3 ions was investigated.(61370049, 61308090, 61405182, 51172252, 51372235, 51472225); International Science
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