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以3-硝基邻苯二甲腈为起始原料,与正戊醇反应合成3-戊氧基邻苯二甲腈(1),然后在高温溶剂1-氯萘中经缩聚反应合成二氯-轴向取代-四-α-(3-戊氧基)锡酞菁(2),2进一步与2-羟基吡啶在N,N-二甲基甲酰胺中合成二-吡啶氧基-轴向取代-四-α-(3-戊氧基)锡酞菁配合物3,同时对相关化合物分别进行了元素分析,IR,1H NMR,UV/Vis,荧光和质谱表征.
3-Pentoxyphthalonitrile (1) was synthesized by the reaction of n-pentanol and 3-nitrophthalonitrile as the starting material, followed by polycondensation reaction in 1-chloronaphthalene, a high temperature solvent to synthesize dichloro - Axially Substituted Tetrakis - (3-Pentyloxy) Tin Phthalocyanine (2), 2 Further Synthesis of Di-Pyridyloxy-2-Hydroxypyridine in N, N-Dimethylformamide Tetra-α- (3-pentyloxy) tin phthalocyanine complex 3 was synthesized and the related compounds were characterized by elemental analysis, IR, 1H NMR, UV / Vis, fluorescence and mass spectrum.