This paper concerns the number and distributions of limit cycles in a Z2-equivariant quintic planar vector field. 25 limit cycles are found in this special planar polynomial system and four different configurations of these limit cycles are also given by using the methods of the bifurcation theory and the qualitative analysis of the differential equation. It can be concluded that H(5) ≥ 25 ＝ 52,where H(5) is the Hilbert number for quintic polynomial systems. The results obtained are useful to study the weakened 16th Hilbert problem.