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四硫代钒酸盐被认为是一类良好的反应前体,利用它们可以方便地得到结构新颖、性质丰富的同(异)核金属硫簇化合物,在无机合成中具有重要的应用价值。本文系统介绍并评述了四硫代钒酸盐作为反应原料在不同反应体系中的反应性能和反应规律以及在合成同核、异核钒化合物中的应用。
Tetrathiovanadate is considered as a kind of good reaction precursors, and it can be conveniently used to obtain the same (different) nuclear metal sulfur cluster compounds with novel structure and abundant properties, which has important application value in inorganic synthesis. This paper systematically introduced and reviewed the reaction performance and reaction rules of tetrathio vanadates as reaction materials in different reaction systems and their application in the synthesis of isonuclear and heteronuclear vanadium compounds.