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Growing competition has prompted enterprises to choose construct Technological Innovation Network to promote innovation,however the innovation network is a risky innovation system, how to carry out a comprehensive risk assessment of the innovation network is particularly important. This paper focused on the technological innovation network risk analysis, used extenics to define which risk levels should these various risk factors in technological innovation network belongs to. And used Shanghai Caohejing hi tech park to do the empirical research, comfirmed risk factors which have the larger influence on technological innovation network.Enterprises can face them as the main objects of enterprise risk management, in order to improve the success rate of the innovation of the enterprise technological innovation network.