Mold manufacturing Extended Enterprise (EE) has the following characteristics: distributed in locality, tight cooperation and frequent information exchange. It needs a collaborative, highly efficient, reliable and intelligent manufacturing management system. The background of the Collaborative Manufacturing is introduced. A mold Collaborative Manufacturing Execution System (c-MES) is proposed. The feature of Web Service platform is analyzed. The necessity and feasibility of importing the Web Service to mold c-MES are discussed. Based on Web Service, the model of mold c-MES is built. Every modules function is described in detail, including the functions it supplies and the mechanism of information interaction among them. The feasibility of mold c-MES model is validated by a real mold manufacturing case.