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通过１，３－二（１－茚基）四甲基二硅氧烷的双锂盐与ＴｉＣｌ４·２ＴＨＦ反应制得硅桥联二（１－茚基）钛化合物（Ｍｅ２ＳｉＯＳｉＭｅ２）［Ｉｎｄ］２ＴｉＣｌ２（１），对其催化氢化得到相应的四氢茚基化合物（Ｍｅ２ＳｉＯＳｉＭｅ２）［ＩｎｄＨ４］２ＴｉＣｌ２（２）。对化合物１和２的单晶进行了Ｘ射线衍射结构分析，它们的晶体都属单斜晶系，Ｐ２１／ｎ空间群。
A silicon-bridged bis (1-indenyl) titanium compound (Me2SiOSiMe2) [Ind] 2TiCl2 (prepared by reaction of the bis lithium salt of 1,3-bis (1-indenyl) tetramethyldisiloxane with TiCl4.2THF 1), which was subjected to catalytic hydrogenation to give the corresponding tetrahydroindenyl compound (Me2SiOSiMe2) [IndH4] 2TiCl2 (2). The single crystals of compounds 1 and 2 were analyzed by X-ray diffraction. All the crystals were monoclinic, P21 / n space group.