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A water-stable zinc-organic framework, Zn(bpda)(hip)·(DMF)(H2O)(1, H2bpda = N4,N4’-di(pyridin-4-yl)biphenyl-4,4’-dicarboxamide, H2 hip = 5-hydroxyisophthalic acid), has been synthesized via solvothermal reactions. Compound 1 exhibits strong fluoresce