Four sets of ternary Ni-Nb-Ta multilayered samples with overall compositions of Ni69Nb8Ta23,Ni55Nb13Ta32,Ni42Nb16Ta42 and Ni29Nb18Ta53,respectively were prepared and subjected to 185 keV xenon ion beam mixing.The experimental results showed that in the four Ni-Nb-Ta multilayered samples,metallic glasses could all be obtained at appropriate doses,supporting the prediction directly from a proven realistic Ni-Nb-Ta interatomic potential through molecular dynamics simulations,and that two different atomic structures were observed,as in the corresponding selected area diffraction patterns,the locations of the diffused bands reflected from the metallic glass phases were observed at different angles for the Ni69Nb8Ta23 and Ni29Nb18Ta53 metallic glasses.Interestingly,Voronoi tellessation analysis indicated that the observed difference in atomic structures could be attributed to the distinct coordinate number spectra,i.e.,the spectrum of the Ni69Nb8Ta23 metallic glass has its coordinate number(CN) equal to 13 as dominating atomic configuration(with a weight of about 27%),whereas for the Ni29Nb18Ta53 metallic glass,CN=14 is the dominating atomic configuration(also about 27%).Moreover,the distinct atomic configurations of the obtained Ni-Nb-Ta metallic glasses could be correlated to the structures of the constituent metals of the ternary Ni-Nb-Ta system,as the first neighbor of fcc is 12 and the sum of the first and second neighbors of bcc is 14,implying the structural heredity did play a role in metallic glass formation. Four sets of ternary Ni-Nb-Ta multilayered samples with overall compositions of Ni69Nb8Ta23, Ni55Nb13Ta32, Ni42Nb16Ta42 and Ni29Nb18Ta53, respectively, were prepared and subjected to 185 keV xenon ion beam mixing. The experimental results showed that in the four Ni-Nb-Ta multilayered samples, metallic glasses could all be obtained at appropriate doses, supporting the prediction directly from a proven realistic Ni-Nb-Ta interatomic potential through molecular dynamics simulations, and that two different atomic structures were observed, as in the corresponding selected area diffraction patterns, the locations of the diffused bands reflected from the metallic glass phases were observed at different angles for the Ni69Nb8Ta23 and Ni29Nb18Ta53 metallic glasses.Interestingly, Voronoi tellessation analysis indicated that the observed difference in atomic structures could be attributed to the distinct coordinate number spectra, ie, the spectrum of the Ni69Nb8Ta23 metallic glass has its coordinate number ( CN) is equal to 13 as a dominating atomic configuration (with a weight of about 27%), while for the Ni29Nb18Ta53 metallic glass, CN = 14 is the dominating atomic configuration Ni-Nb-Ta metallic glasses could be correlated to the structures of the constituent metals of the ternary Ni-Nb-Ta system, as the first neighbor of fcc is 12 and the sum of the first and second neighbors of bcc is 14, implying the structural heredity did play a role in metallic glass formation.