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以卟啉为中心核的树枝状化合物具有特殊的物理、化学及光电性能,其中一个重要特性是具有优良的能量和电子转移性能,近年来研究人员合成了一系列新型的以卟啉为中心核的树枝状化合物,这些化合物在许多领域有着潜在的应用前景。本文综述了近几年来以卟啉为中心核的树枝状化合物的最新研究结果,介绍了一些具有代表性的新型化合物,概述了部分化合物的合成方法及性能,这些化合物由于其结构改变带来的性能变化,分别在光收集材料、发光材料、光动力学疗法、催化剂、传感器等领域有着潜在的应用前景。最后展望了此类化合物的发展方向。
Dendrimers with porphyrin as the central nucleus have special physical, chemical and optoelectronic properties. One of the important properties is their excellent energy and electron transfer properties. In recent years, researchers have synthesized a series of novel porphyrin-centered nuclei Of these dendrimers, these compounds have potential applications in many fields. This review summarizes recent research results on dendrimers with porphyrin as central nucleus, introduces some representative novel compounds, summarizes the synthesis methods and properties of some of the compounds, which are due to the structural changes of these compounds Performance changes, respectively, in light collection materials, luminescent materials, photodynamic therapy, catalysts, sensors and other fields have potential applications. Finally, the development direction of such compounds is forecasted.