【摘 要】
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A novel transition metal ion bridging bis(diphosphopentamolybdates) has been synthesized and characterized by elemental analysis,IR spectrum,UV spectrum and sin
【机 构】
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Institute of Natural Resources and Environmental Science,College of Environment and Planning,Henan U
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A novel transition metal ion bridging bis(diphosphopentamolybdates) has been synthesized and characterized by elemental analysis,IR spectrum,UV spectrum and single-crystal X-ray diffraction.The single-crystal structure analysis shows that the compound consists of seven charge-compensating 2,2’-biimidazole cations (BIIM=2,2’-biimidazole) and one dumbbell-like [Mn(H2O)4(P2Mo5O23)2]10-heteropolyanion which is constructed by two [P2Mo5O23]6-clusters bridged through one [Mn(H2O)4]2+ cation.
A novel transition metal ion bridging bis (diphosphopentamolybdates) has been synthesized and characterized by elemental analysis, IR spectrum, UV spectrum and single-crystal X-ray diffraction. The single-crystal structure analysis shows that the compound consists of seven charge-compensating 2 , 2’-biimidazole cations (BIIM = 2,2’-biimidazole) and one dumbbell-like [Mn (H2O) 4 (P2Mo5O23) 2] 10-heteropolyanion which is constructed by two [P2Mo5O23] 6-clusters bridged through one [ Mn (H2O) 4] 2+ cation.
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