论文部分内容阅读
钴氰化钠与铁氰化钠结构类似,而其在固/液界面上的电子转移特性却并不显著.使用扫描电化学显微镜(SECM)构建了fL~pL体积的电化学微体系.在微体系中溶剂蒸发,电解质则会浓缩结晶.当电活性物质与支持电解质的晶格参数匹配时,二者可发生共结晶形成固体溶液.本文采用该方法制得钴氰化钠/氯化钠固体溶液微晶体,结合微加工技术构建了固体电极/固体溶液界面,该钴氰化钠在固体溶液中即有很好的电子转移特性.
The structure of sodium cobalt cyanide is similar to that of sodium ferricyanide, and the electron transfer properties of the product are not significant at the solid / liquid interface. The electrochemical microlocatl system with volume of fL ~ pL was constructed by scanning electron microscopy (SECM) When the solvent is evaporated in the micro-system, the electrolyte will be concentrated and crystallized, and when the lattice parameters of the electro-active material and the supporting electrolyte match, the two may co-crystallize to form a solid solution.In this paper, sodium cobalt cyanide / sodium chloride Solid solution microcrystal, combined with micro-processing technology to build a solid electrode / solid solution interface, the sodium cobalt cyanide in solid solution that has good electron transfer properties.