【摘 要】
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IntroductionRecently, late-transition-metal complexes have been extensively used as both inorganic and organometallic catalysts[1]. Some complexes have been dev
【机 构】
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College,Key Laboratory for Supramolecular Structure and Materials of Ministry of Education,State
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IntroductionRecently, late-transition-metal complexes have been extensively used as both inorganic and organometallic catalysts[1]. Some complexes have been developed as the novel olefin polymerization catalysts[2-4] and copolymerization catalysts for ethylene and polar comonomers[5] due to their lower oxophilicity and presumed greater functional tolerance. Moreover, compounds with imine ligands have received more attention and have been reported for the synthesis method, structure, mechanism and application[6-9]. In this contribution, we report the synthesis of the dimericβ-diketiminato Co(Ⅱ)chloride complex:
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