STUDIES OF CATALYTIC PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS

来源 :Journal of Natural Gas Chemistry | 被引量 : 0次 | 上传用户:softguner
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The aetivities of Ni/Al2O3 and Pt-doped Ni/Al2O3 catalysts forpartial oxidation of methane to synthesis gas have been studied by using afixed-bed flow reactor It was found by examining the effects of dopedamount of Pt on catalytic properties of catalysts that the activity andselectivity for CO and H2 of Pt- doped Ni/Al2O3 were much better than thatof Ni/Al2O3 catalyst The interaction between Pt and Ni in the catalyst wasinvestigated by temperature-programmed reduction CO2-temperature programmed edsroption and CO-temperature-programmed desorption Theresults showed that Pt promoted the reduction of Ni and affected the CO andCO2 adsorption capacity of Pt-doped Ni-Al2O3 catalyst This indicated thatthere might be some strong interaction between Pt and Ni which enhancedthe activity and stability of Pt-dopedNi-Al2O3 catalyst. The aetivities of Ni / Al2O3 and Pt-doped Ni / Al2O3 catalysts for partial oxidation of methane to synthesis gas have been studied by using afixed-bed flow reactor It was found by examining the effects of dopedamount of Pt on catalytic properties of catalysts that the activity andselectivity for CO and H2 of Pt-doped Ni / Al2O3 were much better than that of Ni / Al2O3 catalyst The interaction between Pt and Ni in the catalyst was investigated by temperature-programmed reduction CO2-temperature programmed edscript and CO-temperature-programmed desorption The results showed showed that Pt promoted the reduction of Ni and affected the CO andCO2 adsorption capacity of Pt-doped Ni-Al2O3 catalyst This indicated that it might might some strong interaction between Pt and Ni which enhanced the activity and stability of Pt-doped Ni-Al2O3 catalyst.
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