Ring strain strategy for the control of regioselectivity. Gold-catalyzed anti-Markovnikov cycloisome

来源 :科学通报：英文版 | 被引量 : 0次 | 上传用户：qg101213

【摘要】

：

Gold-catalyzed nucleophilic addition to terminal alkynes has received considerable interest in the past decade, as this chemistry offers a highly efficient and

【作者】

：

Chao Shu Long Li Tong-De Tan D

【机构】

：

StateKeyLaboratoryofPhysicalChemistryofSolidSurfacesandTheKeyLaboratoryforChemicalBiologyofFujianPro

【出处】

：

科学通报：英文版

【发表日期】

：

2017年5期

【基金项目】

：

This work was supported by the National Natural Science Foundation of China （21272191, 21572186 and 21622204）, the Natural Science Foundation of Fujian Province for Distinguished Young Scholars （2015J

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

Gold-catalyzed nucleophilic addition to terminal alkynes has received considerable interest in the past decade, as this chemistry offers a highly efficient and regioselective way for CAC, CAH and CAX bond formation. However, such a nucleophilic addition m

其他文献

IP-IO and fractalkine induce cytotoxic phenotype of murine NK cells

We characterized the murine NK cell subsets of the tumor microenvironment(TME)with low expressions of CD16 and NKG2D and investigated the chemokines that deter

期刊

NK细胞细胞毒性趋化因子诱导蛋白小鼠NKG2D表型细胞亚群Chemokines NK cell Activating receptors

Platinum drugs： from Pt（Ⅱ） compounds, Pt（Ⅳ） prodrugs, to Pt nanocrystals/nanoclusters

Platinum(Pt) based drugs, such as cisplatin, are widely used as anti-cancer agents, but their severe adverse reactions and resistance of cancer patients have li

期刊

铂(Ⅳ)前体药物纳米晶化合物纳米团簇癌症患者抗癌机制抗癌药物PlatinumPt（Ⅱ）Pt（Ⅳ）Pt nanocrystals/nanoc

Simple and cost-effective methods for precise analysis of trace element abundances in geological mat

Inductively coupled plasma mass spectrometry(ICP-MS) is the most commonly used technique to determine the abundances of trace elements in a wide range of geolog

期刊

ICP-MS元素丰度地质材料精确分析经济电感耦合等离子体质谱VBA程序干扰校正Inductively coupled plasma mass s

Design and fabrication of 1-D semiconductor nanomaterials for high-performance photovoltaics

迄今为止，由为大规模推广的 photovoltaics 的太阳能的划算的利用仍然保持挑战性。进一步的费用最小化和效率最大化通过材料消费的减小，设备制造以及设备结构和几何学的优化的

期刊

一维纳米材料半导体纳米材料光电器件光伏太阳能性能设备制造成本最小化半导体材料One-dimensional nanomaterialsPhot

Subsurface reconstruction and saturation of surface bonds

Surface reconstructions and stabilization mechanisms have been great challenges for insulators. Based on accurate determination of the long-sought atomic struct

期刊

SPINELOXIDESSURFACEreconstructionTransmissionelectronmicroscopyDensityfu

Shape-controlled Pt nanocubes directly grown on carbon supports and their electrocatalytic activity

Synthesis of shape-controlled Pt nanocrystals is substantial and important for enhancing chemical and electrochemical reactions.However,the removal of capping a

期刊

铂纳米粒子电催化活性形状控制甲醇氧化直接生长碳载体电化学反应PT/C催化剂Platinum Nanocube Shape-control Kin

Ultra-low noise measurements of nanopore-based single molecular detection

Nanopore is an ultra-sensitive electrochemical technique for single molecular detection in confined space.To suppress the noise in detection of the weak current

期刊

单分子检测噪声测量纳米孔噪声电压薄膜电容仪表系统电化学技术密闭空间Nanopore Membrane capacitance Current a

In-situ structure reconstitution of NiCo2Px for enhanced electrochemical water oxidation

Gaining insight into the structure evolution of transition-metal phosphides during anodic oxidation is significant to understand their oxygen evolution reaction

期刊

Investigation of the hydrogen adsorbed density inside the pores of MOF-5 from path integral grand ca

我们在 MOF-5 上检验氢的吸附等温线的高密度限制。等温线在压力范围上用量 GCMC 模拟被计算： 0-150 ? atm ( 1 ? atm ?=? 1.01325 ??猼'T资??????￣?猼'T???????????

期刊

吸附等温线临界温度超临界高密度蒙特卡罗路径积分孔内氢Hydrogen adsorption isotherms MOF-5 Metal-or

Out-of-time-order correlation for many-body localization

In this paper we first compute the out-of-time-order correlators(OTOC) for both a phenomenological model and a random-field XXZ model in the many-body localized

期刊

时间相关定位系统多体时间序列相关RENYI熵XXZ模型唯象模型量子系统Out-of-time-order correlationMany-bod

Ring strain strategy for the control of regioselectivity. Gold-catalyzed anti-Markovnikov cycloisome

与本文相关的学术论文