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从烯丙基甲基苯基氨基硅烷出发,经烷基化反应,得到(E)-烯基氨基硅烷,然后水解成(E)-烯基硅醇。研究了烯丙基氨基硅烷碳负离子烷基化反应的区域选择性,建立了去除α-异构体的方法。
Starting from allyl methylphenylaminosilane, alkylation reaction gives (E) -alkenylaminosilane which is then hydrolysed to (E) -alkenylsilanol. The regioselectivity of the alkylation of allylaminosilane with carbon anion was studied and a method of removing α-isomer was established.