论文部分内容阅读
在有机强碱1,8-二氮杂双环[5,4,0]+-7烯(简称DBU)存在下的醇溶剂中,用“分子碎片”与“金属离子”[Pd(Ⅱ)]通过模板反应合成了未见报道的四溴-2,3-萘酞菁钯(Ⅱ)[PdNcBr4]。在元素分析,IR光谱表征的基础上,研究了其在氧气气氛中的热稳定性、非水体系的电子吸收光谱。
In the presence of organic strong base 1,8-diazabicyclo [5,4,0] -7-ene (abbreviated as DBU) in alcohol solvent, “molecular fragment” and “metal ion” No reported tetrabromo-2,3-naphthalocyanine palladium (II) [PdNcBr4] was synthesized through the template reaction. On the basis of elemental analysis and IR spectrum characterization, the thermal stability in oxygen atmosphere and the electron absorption spectrum of non-aqueous system were studied.