论文部分内容阅读
α－（6-甲氧基-2-萘基）-乙醇在催化剂的作用下，与甲醇和CO发生羰基化反应，一步生成α－（6-甲氧基-2-萘基）丙酸甲酯（萘晋生申酯）。应用气相色谱-质谱联用技术，对这个反应过程中生成的各种化合物进行了分析，获得两个中间产物6-甲氧基萘乙烯和1-甲氧基-1-（6’-甲氧基-2’-萘基）乙烷的GC／MS数据资料，为推测该催化反应机理提供了可靠的依据。
In the presence of a catalyst, α- (6-methoxy-2-naphthyl) -ethanol undergoes carbonylation reaction with methanol and CO to form α Ester (naphthalene tocopheryl acetate). The various compounds generated during this reaction were analyzed by GC-MS to obtain two intermediates, 6-methoxynaphthalene and 1-methoxy-1- (6’-methoxy 2-naphthyl) ethane GC / MS data provide a reliable basis for speculating the catalytic reaction mechanism.