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以4-苯乙烯基吡啶(4SZ)为质子受体,侧链含苯甲酸的苯乙烯/马来酸单酯共聚物(ME-SMA)为质子供体,四氢呋喃为溶剂,制备高分子氢键复合物。DSC和POM的结果表明该氢键复合物在146~204℃呈现向列相液晶态。IR结果证实了羧基和吡啶环的分子间氢键代替了羧基间的分子间氢键。
Using 4-styrylpyridine (4SZ) as proton acceptor, side-chain styrene / maleic acid monoester copolymer containing benzoic acid (ME-SMA) as proton donor and tetrahydrofuran as solvent, Complex. DSC and POM results show that the hydrogen bonding complex exhibits nematic liquid crystal state at 146 ~ 204 ℃. The IR results confirm that the intermolecular hydrogen bonds of the carboxyl group and the pyridine ring replace the intermolecular hydrogen bonds between the carboxyl groups.