以环己烷二甲醇和卤代芳烃为原料,CuBr作为催化剂,在无配体条件下,通过C-O交叉偶联反应合成了脂肪-芳香二醚类化合物。对活性较低的脂肪族二元醇和卤代烃的交叉偶联反应进行了初步的探索,考察了偶联反应的影响因素,对产物的结构进行了结构确认和荧光性能的研究。 Using cyclohexane dimethanol and halogenated aromatics as raw materials, CuBr as catalyst was synthesized in the absence of ligands by C-O cross-coupling reaction of aliphatic-aromatic diethers. The cross-coupling reaction of aliphatic diols and halohydrocarbons with lower activity was primarily explored. The influencing factors of the coupling reaction were investigated. The structure of the product was confirmed by its structure and fluorescence properties.