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A one-dimensional (1D) supramolecular rare earth complex [Nd(NO3)2L2-(C3H6O)][NdL(NO3)4]} (L = N-(6-(4-methylpyridinyl))ketoacetamide) has been prepared and characterized by elemental analysis, IR and electronic spectroscopy, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic system, space group P1 with a = 0.9146(6), b = 1.2581(8), c = 2.2316(14) nm, α = 99.352(10), β = 97.209(9), γ = 103.935(9)°, V = 2.422(3) nm3, Dc = 1.776 g/cm3, C33H42N12Nd2O25, Mr = 1295.27, Z = 2, F(000) = 1288, μ = 2.217 mm-1, R = 0.0508 and wR = 0.1046 for 5173 observed reflections (I > 2σ(I)). In the structure of the title complex, one-dimensional supramolecular double-chains are formed by intermolecular hydrogen bonding interactions.
A one-dimensional (1D) supramolecular rare earth complex [Nd (NO3) 2L2- (C3H6O)] [NdL (NO3) 4]} has been prepared and characterized by elemental analysis, IR and electronic spectroscopy, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic system, space group P1 with a = 0.9146 (6), b = 1.2581 (8), c = (9), γ = 103.935 (9) °, V = 2.422 (3) nm3, Dc = 1.776 g / cm3, C33H42N12Nd2O25, Mr = 1295.27, Z = In the structure of the title complex, one-dimensional supramolecular double-chains are F (000) = 1288, μ = 2.217 mm -1, R = 0.0508 and wR = 0.1046 for 5173, formed by intermolecular hydrogen bonding interactions.