A Kinetic Study of Selective Hydrogenation of Carbon Monoxide to C_2 Oxygenates on Rh-Mn-Li-Fe/SiO_2

来源 :Journal of Natural Gas Chemistry | 被引量 : 0次 | 上传用户:a6532460
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The kinetics of CO hydrogenation for the synthesis of C_2 oxygenates over Rh-Mn-Li-Fe/SiO_2was investigated. Kinetic parameters for the formation of ethanol, acetaldehyde, C_2 oxygenates, methanoland methane were obtained. The activation energy, H_2 and CO dependence orders for ethanol and ac-etaldehyde formation differed greatly, the large difference seemed to imply that they were formed throughdifferent intermediates. The kinetics of CO hydrogenation for the synthesis of C 2 oxygenates over Rh-Mn-Li-Fe / SiO 2 was investigated. Kinetic parameters for the formation of ethanol, acetaldehyde, C_2 oxygenates, methanoland methane were obtained. The activation energy, H_2 and CO dependence orders for ethanol and ac-etaldehyde formation differed greatly, the large difference seemed to imply that they were formed throughdifferent intermediates.
其他文献
国家一级美术师李秀林接受过高等绘画艺术专业的系统教育,不仅具有扎实的绘画基本功,在书法艺术方面也有较高的修养。画家敏于思,善于悟,勤于作。书风、画风亦如其人,粗犷大
The interaction of the anticancer drug hypocrellin B (HB) or the mono-cysteine substituted hypocrellin B (MCHB) and calf thymus deoxyribonucleic acid (CT-DNA)
The V 2O 5 sol was fabricated by ultra fast quenching.The vanadium with low valence (V 4+ ) was found in V 2O 5 xerogel films by XPS analysis.The techn
在湖南平江县财会领域,提起县国库集中支付局副局长李双凤的名字,几乎无人不知,无人不晓。她被大家亲切地称为凤姐,是业内屈指可数的传奇人物。这不仅是因为她30年如一日以算
美国研究人员日前报告说:他们开发出一种实验性猿类免疫缺陷病毒疫苗,可大幅降低恒河猴感染猿类艾滋病病毒的风险。这一研究成果为开发人类艾滋病疫苗提供了新思路。这项由哈
Unsymmetrical sulfides can be generated by the reaction of chlorine substituted aromatic compounds in sulfoxide in the presence of fluorine anion in fair yield.
A novel b-cyclodextrin dimer bearing 2, 9-diformyl-1, 10-phenanthroline tether 4 has been synthesized and its inclusion complexation behavior with two triangula
我们同在一个蓝星球,却像是相约了很久。做个你我都懂的手势,就是朋友,OK G20!OK杭州!
视网膜脱离患者的未脱离眼称“健眼”。自1986年9月~1987年12月我们对110例“健眼”在暗适应情况下进行了视网膜电图(ERG)检测,同时与对照组进行对比研究。现将结果报告如下
他不是公安干警,可是人们有困难都愿找他帮助;他也不是工商管理干部,可是个体户们都乐意听他的话;他更不是银行信贷员,可大家缺钱少款都来找他挪借。在人们眼中他就是“靠山