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A novel Ru(Ⅱ) complex [(bpy)2Ru(PBC)](PF6)2 (PBC = N-[4-(9-carbazole)butyl]-2-(2-pyridyl)benzimidazole) has been synthesized and verified by 1H NMR, elemental analysis and X-ray crystallography. The crystal (C48H40F12N8P2Ru, Mr = 1119.89) belongs to the t