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The adsorption of acetonitrile and its co-adsorption with CO on fresh Mo2C/Al2O3 catalyst have been studied by insitu FT-IR spectroscopy.Linearly adsorbed CH3CN and CH3CH2NH2 were formed after CH3CN adsorption on the Mo2C/Al2O3 catalyst.The appearance of a strong band at 1578 cm 1 indicates that CH3CN was reactive with hydrogen on the Mo2C/Al2O3 catalyst.