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报导了新近合成的二硫纶 5 -硝基菲咯啉铁 ( )配合物 Fe L L′(L =m nt2 - ,maleonitriledithiolate;L′=5 -NO2 - phen,5 - nitri- 1,10 - phenanthroline)透射电镜和粉末样品的变温磁化率 ,发现标题配合物是纳米级 (颗粒直径约15 0～ 5 0 nm)的微晶粉体 ,具有显著的顺磁性 ,形成四配位的高自旋态构型 ,并且呈现一定的自旋交叉性 .探讨了这种配合物作为磁功能分子材料应用于高科技领域中的可能性
The recent reports on the synthesis of Fe LL ’(L = m nt2 -, maleonitriledithiolate; L’ = 5 - NO2 - phen, 5 - nitri - 1,10 - phenanthroline ) Transmission electron microscopy and powder samples, the title complex was found to be nanocrystalline (about 15 0 ~ 500 nm in diameter) crystallite powder with significant paramagnetic properties and the formation of a four-coordinated high-spin configuration , And showed a certain degree of spin-crossing.The possibility of using this complex as a magnetic functional molecular material in high-tech fields