Full recycling of spent lithium ion batteries with production of core-shell nanowires//exfoliated gr

来源 :能源化学 | 被引量 : 0次 | 上传用户:goodhope9010
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A novel process is reported which produces an asymmetric supercapacitor through the complete recycling of end-of-life lithium ion batteries.The electrodic powder recovered by industrial scale mechanical treatment of spent batteries was leached and the dissolved metals were precipitated as mixed metals carbonates.Nanowires battery-type positive electrodes were produced by electrodeposition into nanoporous alumina templates from the electrolytic baths prepared by dissolution of the precipitated carbonates.The impact of the different metals contained in the electrodic powder was evaluated by benchmarking the electrochemical performances of the recovered nanowires-based electrodes against electrodes produced by using high-purity salts.Presence of inactive Cu in the nanowires lowered the final capacitance of the electrodes while Ni showed a synergistic effect with cobalt providing a higher capacitance with respect to synthetic Co electrodes.The carbonaceous solid recovered after leaching was indepth characterized and tested as negative electrode.Both the chemical and electrochemical characterization indicate that the recovered graphite is characterized by the presence of oxygen functionalities introduced by the leaching treatment.This has led to the obtainment of a recovered graphite characterized by an XPS C/O ratio,Raman spectrum and morphology close to literature reports for reduced graphene oxide.The asymmetric supercapacitor assembled using the recovered nanowires-based positive electrodes and graphite as negative electrodes has shown a specific capacitance of 42 F g-1,computed including the whole weight of the positive electrode and recovered graphite,providing a maximum energy density of ~9 Wh kg-1 and a power density of 416 W kg-1 at 2.5 mA cm-2.
其他文献
Nickel-iron layered double hydroxides(NiFe LDHs) have been identified as one of the best promising electrocatalysts-candidates for oxygen evolution reaction(OER). However, the catalytic activity effected by interlayer water molecules is ignored and rarely
Zero-dimensional(0D)carbon quantum dots(CQDs),as a nanocarbon material in the carbon family,have garnered increasing attention in recent years due to their outs
Bismuth sulfide (Bi2S3) has attracted particular interest as a potential anode material for sodium-ion batteries (SIBs).However,the low electrical conductivity
Electrospinning has been proven as a highly versatile fabrication method for producing nano-structured fibres with controllable morphology,of both the fibres th
Electrochemical nitrogen fixation via a convenient and sustainable manner,exhibits an intriguing prospect for ammonia generation under ambient conditions.Currently,the design and development of high-efficiency and low-cost electrocatalysts remains the maj
Sodium-ion storage devices are highly desirable for large-scale energy storage applications owing to the wide availability of sodium resources and low cost.Tran
Differential electrochemical mass spectrometry (DEMS) is one of the most powerful techniques for both the mechanistic and kinetic study of complicated electroca
Rechargeable lithium metal batteries(LMBs)have gained much attention recently.However,the short lifespan and safety issues restrict their commercial application
Sodium-ion batteries are considered as promising alternatives to lithium-ion batteries,owing to their low cost and abundant raw materials.Among the several cand
Controllable fabrication of Fe-N-C based single-atom catalysts (SACs) for enhanced electrocatalytic performance is highly desirable but still challenging.Here,a