Suburbanization in large cities is an important phenomenon in the process of urbanization development in China in recent decades, which plays a very important role in promoting city development, whereas some side effects on the eco-environment appeared at the same time. This paper, taking Xi＇an City in China as a case study site, analyzed the features of population suburbanization and industry suburbanization and pointed out the impacts of suburbanization on urban eco-environment. Based on the research, suggestions of countermeasures for urban planning and municipal management of Xi＇an City in protecting urban eco-environment and conserving natural ecology were put forward in the end.