真空沉积TCNQ薄膜的手性分形结构

来源 :物理化学学报 | 被引量 : 0次 | 上传用户:xi19870623
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The unique two dimensional chiral “seahorse” like fractal aggregates of pure tetracyanoquinodimethane (TCNQ) and PANI TCNQ complex thin films,deposited by vacuum evaporation,were observed and reported.The influence of some experimental factors,such as electrostatic field,substrates and deposition rate,on the fractal pattern formation was discussed in detail.It was found that the electrostatic effects,induced by charged particles,do not play a crucial role in the pattern growth process.We suggest that the key to the formation of the patterns lies in the special molecular structure and the unique process of the crystal growth of TCNQ thin films,and a new growth model was proposed.ChiralFractalPatt The unique two dimensional chiral “seahorse” like fractal aggregates of pure tetracyanoquinodimethane (TCNQ) and PANI TCNQ complex thin films, deposited by vacuum evaporation, were observed and reported. The influence of some experimental factors, such as electrostatic fields, substrates and deposition rate , on the fractal pattern formation was discussed in detail. It was found that the electrostatic effects, induced by charged particles, do not play a crucial role in the pattern growth process. We suggest that the key to the formation of the patterns lies in the special molecular structure and the unique process of the crystal growth of TCNQ thin films, and a new growth model was proposed. Chiral Fractal Pay
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