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将以三齿2,6 双(苯并咪唑)吡啶为配体的Cu(I)离子络合物用作A TRP引发体系的组分之一,并成功地实现了对烯类单体的自由基聚合.聚合过程具有明显的ATRP聚合特征.和几种具不同结构胺配体构成的Cu(I)络合物的聚合速度结果相比较,本工作的结果基本符合烷基胺≈吡啶>亚胺>芳基胺的序列关系.
The Cu (I) ion complex using tridentate 2,6-bis (benzimidazole) pyridine as a ligand was used as one of the components of the ATRP initiator system, and successfully achieved the freedom of the ethylenic monomer Base polymerization.The polymerization process has obvious ATRP polymerization characteristics.Compared with the results of the polymerization rate of several Cu (I) complexes with different structure amine ligands, the results of this work are basically in line with alkylamine ≈ pyridine> Amine> arylamine.