Study on transport of Dy(Ⅲ) by dispersion supported liquid membrane

来源 :稀土学报(英文版) | 被引量 : 0次 | 上传用户:houchen02
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The transport of Dy(Ⅲ) through a dispersion supported liquid membrane (DSLM) consisting of polyvinylidene fluoride mem-brane (PVDF) as the liquid membrane support and dispersion solution including HC1 solution as the stripping solution and 2-ethyl hexyl phosphonic aeid-mono-2-ethyl hexyl ester (PC-88A) dissolved in kerosene as the membrane solution, was studied. The effects of pH value, initial concentration of Dy(Ⅲ) and different ionic strength in the feed phase, volume ratio of membrane solution and stripping solution, con-centration of HC1 solution, concentration of carder, different stripping agents in the dispersion phase on transport of Dy(Ⅲ) were also inves-tigated, respectively. As a result, when the concentration of HCI solution was 4.0 mol/L, concentration of PC-88A was 0.10 mol/L, and vol-ume ratio of membrane solution and stripping solution was 40:20 in the dispersion phase, and pH value was 5.0 in the feed phase, the trans-port effect of Dy(Ⅲ) was the best. Ionic strength had no obvious effect on transport of Dy(Ⅲ). Under the optimum condition studied, when initial concentration of Dy(Ⅲ) was 0.8×10-4 mol/L, the transport rate of Dy(Ⅲ) was up to 96.2% during the transport time of 95 min. The kinetic equation was developed in terms of the law of mass diffusion and the theory of interface chemistry. The diffusion coefficient of Dy(Ⅲ) in the membrane and the thickness of diffusion layer between feed phase and membrane phase were obtained and the values were 1.99×10-7 m2/s and 15.97 μm, respectively. The results were in good agreement with experimental results.
其他文献
The nanometer Al2O3 dispersion strengthened NiCoCrAlY high-temperature protective coatings by crosscurrent CO2 laser on Ni-based superalloy GH4033 were produced
To inhibit chips burning in the high-speed cutting of Ti-6Al-4V, nitrogen gas with 0.7 MPa pressure was ejected at the milling zone. The high speed flowing of n
Zinc phosphate coatings formed on 6061-Al alloy, after dipping in phosphating solutions containing different amounts of Y2O3(yttrium oxide), were studied by sca
Mn segregation at austenite/ferrite interface is studied in a Fe-C-Mn-Si alloy held at 656℃.Mn is partitioned during the growth of ferrite and as a result, a M
TiB2 and Dy2O3 were used as codeposited particles in the preparation of Ni-TiB2-Dy2O3 composite coatings to improve its per-formance. Ni-TiB2-Dy2O3 composite co
Electrical conductivity of NaF-AlF3 melts was measured by continuously varying cell constant(CVCC) technique. Relationships between equivalent conductivity at 9
The TiN/Ti multilayer was deposited on Ti-811 alloy surface by magnetron sputtering(MS) technique for improving fretting fatigue(FF) resistance of the titanium
Three-dimensionally ordered macro-porous(3DOM) TiO2 and ceria-modified 3DOM TiO2 supported platinum catalysts were pre-pared with template and impregnation meth
γ-mercapto-propyl trimethoxysilane (MPTS) and γ-methacryloxy propyltrimethoxysilane (MPTES) were self-assembled on a hy-droxylated glass substrate to form a t
Powdering/exfoliating of coatings and scratching are the main forms of surface damage in the forming of galvanized steels and high strength steels (HSS), which