【摘 要】
：
A new stepping chain {[Cu(1,10-phen)]2(H2O3PCH2C6H4C6H4CH2PO3H)2(HO3P- CH2C6H4C6H4CH2PO3H)}n 1 (C66H60Cu2N4O18P6) has been hydrothermally synthesized and charac
【机 构】
：
State Key Laboratory of Structural Chemistry
论文部分内容阅读
A new stepping chain {[Cu(1,10-phen)]2(H2O3PCH2C6H4C6H4CH2PO3H)2(HO3P- CH2C6H4C6H4CH2PO3H)}n 1 (C66H60Cu2N4O18P6) has been hydrothermally synthesized and charac- terized by single-crystal X-ray diffraction. It belongs to monoclinic, space group C2/c with a = 25.6114(4), b = 18.3781(2), c = 16.5180(3) (A), β= 124.0610(10)o, V = 6441.00(17)(A)3, Z = 4, Dc = 1.557 g/cm3, ((Mo-Kα) = 0.887 mm-1, F(000) = 3104, the final R = 0.0853 and wR = 0.1676 for 5585 independent reflections.
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