【摘 要】
:
Rare earth oxides doped hafnia ceramics,with a formula of Hf0.76LnxY0.24-xO1.88 (Ln =Gd,Yb,Gd + Yb or La + Yb),were prepared by solid state sintering at 1500 ℃
【机 构】
:
School of Materials Science and Engineering, Beihang University, Beijing, 100191, China;School of Ma
论文部分内容阅读
Rare earth oxides doped hafnia ceramics,with a formula of Hf0.76LnxY0.24-xO1.88 (Ln =Gd,Yb,Gd + Yb or La + Yb),were prepared by solid state sintering at 1500 ℃.The effects of the rare earth oxides on the microstructures,sintering resistance,and thermo-physical properties of the doped hafnia ceramics were investigated.Results show that the Gd-Y,Yb-Y or Gd-Yb-Y co-doped hafnia ceramics remain the same defect fluorite (F) structure,while the La-Yb-Y co-doped hafnia revealing coexistence of pyrochlore (P)and fluorite structures.Yb-Y co-doped samples exhibited much better sintering resistance compared with Gd-Y and Gd-Yb-Y co-doped samples.The coexistence of P and F phases is beneficial to improved sintering capability.The thermal conductivities of the Gd-Y,Yb-Y and Gd-Yb-Y doped samples are relatively lower (1.4-1.7 W m-1 K-1 at 1200 ℃),but for the La-Yb-Y co-doped samples,the thermal conductivity increases dramatically with temperature due to increased thermal radiation at high-temperature.The average thermal expansion coefficients (TECs) of the Gd-Y,Yb-Y and Gd-Yb-Y co-doped samples are as high as ~10.3 × 10-6 K-1 in temperature range between 200-1200 ℃.
其他文献
The concept of all-solid-state batteries provides an efficient solution towards highly safe and long-life energy storage,while the electrolyte-related challenge
The crevice corrosion behavior of Alloy 690 was investigated in high-temperature chloride solution containing different concentrations of thiosulfate (S2O32-) a
The effect of thermal exposure on microstructure and creep properties of a fourth-generation nickelbased single crystal superalloy was investigated.The thermal
Vanadium redox flow battery (VRB),as the most promising large-scale electrical energy storage units,has attracted extensive attention.Amphoteric ion exchange me
Brittleness is a bottleneck hindering the applications of fruitful functional properties of Ni-Mn-based multiferroic alloys.Recently,experimental studies on B a
合成并研究了5-氯-3-硝基螺吡喃光谱性质及特异性识别.研究结果表明,5-氯-3-硝基螺吡喃具有溶剂化显色效应,闭环结构SP和开环结构MC分别在非极性和极性溶剂中稳定存在;该螺吡
Variant selection during the martensitic transformation in steels may play an important role in determining the transformation kinetics and the resulting mechan
Due to the demands for high performance and ecological and economical alternatives to conventional lithium-ion batteries (LiBs),the development of lithium-sulfu
High-performance electromagnetic (EM) wave absorbers,covalently bonded reduced graphene oxide-Fe3O4 nanocomposites (rGO-Fe3O4),are synthesized via hydrothermal