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A unique ionic hybrid material[C_6H_(12)N_5O]_3[(PO_4)W__(12)O_(36)]·5H_2O has been synthesized from the reaction of((1H-tetrazole-5- yl)methyl)morpholine andα-H_3[(PO_4)W_(12)O_(36)]·21H_2O.It has successfully been characterized by elemental analysis,IR and ~1H NMR spectroscopies,TGA and single-crystal X-ray diffraction method.The title compound is constructed from the three [C_6H_(12)N_5O]~+ cations andα-Keggin[(PO_4)W_(12)O_(36)]~(3-) polyoxoanion.The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like(2D/∞)[(PO_4)W_(12)O_(36)]~(3-)) which forming via van der Waals interactions along the x axis.
A unique ionic hybrid material [C_6H_ (12) N_5O] _3 [(PO_4) W_ (12) O_ (36)] · 5H_2O has been synthesized from the reaction of H_3 [(PO_4) W_ (12) O_ (36)] · 21H_2O.It has been successfully characterized by elemental analysis, IR and ~ 1H NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is constructed from the three [C_6H_ (12) N_5O] ~ + cations and α-Keggin [(PO_4) W_ (12) O_ (36)] ~ (3-) polyoxoanion.The most remarkable structural feature of this hybrid can be described as two-dimensional (12) O_ (36)] ~ (3-)) which formed via van der Waals interactions along the x axis.