【摘 要】
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The title compound has been prepared and characterized by elemental analysis, infrared spectra, NMR and thermal analyses, and its crystal structure was determin
【机 构】
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School of Chemical Engineering
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The title compound has been prepared and characterized by elemental analysis, infrared spectra, NMR and thermal analyses, and its crystal structure was determined by X-ray diffraction method. The crystal crystallizes in the monoclinic system, space group C2/c with a = 2.3066(5), b = 0.53320(11), c = 2.3236(5) nm, β = 102.76(3)°, V = 2.7872(10) nm3, Mr = 612.67, Z = 4, Dc = 1.460 g/cm3, R = 0.0570 and wR = 0.1271. In the title compound, two 4-isoni- azidylthioformyl units are bridged by S-S bond (0.2037(3) nm). The Na ions are linked by O(4), O(4A), O(1) and O(1A) to form a one-dimensional hydration sodium coordination polymer. The Na ion is coordinated by a meridional arrangement of the six O atoms to assume a slightly distorted octahedron as a result of intermolecular hydrogen bonds. The thermal analytical data indicate that it decomposes completely at the temperature of 609.26 ℃.
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