前言在催化反应的络合活化过程中,多位配位有时可以发挥协同效应,从而可能比单核金属络合物的催化作用更为有效。金属原子簇化合物,特别是高核簇可以作为金属或合金的模拟物进行研究。Muetterties曾指出原子簇催化反应的范围跟多相催化反应十分相似。近年来钌簇化合物的研究有了深入的发展,这和 C_1化学的开发有着十分密 INTRODUCTION In the complexation and activation of catalysis, multiple coordination may sometimes exert a synergistic effect, which may be more effective than the catalysis of mononuclear metal complexes. Metal cluster compounds, especially high-core clusters, can be studied as metal or alloy mimics. Muetterties has pointed out that the scope of atomic catalysis catalysis with heterogeneous catalytic reaction is very similar. In recent years, the research of ruthenium cluster compounds has been further developed, which is very close to the development of C_1 chemistry