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A quantum mechanical calculation was performed to study the Translation Vibration( T V ) energy transfer of a colinear OH+O/OD+O system, for which Delves coordinates and R matrix propagatation methods were applied to a Mulius Blint potential energy surface. The calculated result of the T V energy transfer probability shows strong oscillation phenomena and the collision delay time of the title system was in the 10 -15 -10 -12 s time scale. The kinetic isotope effect was discussed in this work too.
A quantum mechanical calculation was performed to study the translation Vibration (TV) energy transfer of a colinear OH + O / OD + O system, for which Delves coordinates and R matrix propagation methods were applied to a Mulius Blint potential energy surface. result of the TV energy transfer probability shows strong oscillation phenomena and the collision delay time of the title system was in the 10 -15 -10 -12 s time scale. The kinetic isotope effect was discussed in this work too.